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Prof. Fu-Yu Tsai

蔡福裕 博士

實驗室:奈米材料及有機金屬實驗室 詳細資料

學歷:

    國立台灣大學 化學博士
    國立台灣大學 化學碩士
    私立中原大學 化學學士

辦公室:分子館 2 樓 (02)27712171 #2437 

研究室:分子館 4 樓 (02)27712171 #2425

E-mail:fuyutsai@ntut.edu.tw


簡歷

  1. 國立台北科技大學 教授 (2011, 08— )
  2. 國立台北科技大學 副教授 (2008, 02—2011, 07)
  3. 國立台北科技大學 助理教授 (2004, 02—2008, 01 )
  4. 國立臺灣大學 客座助理研究員 (2001, 04—2004, 01)
  5. 日本北海道大學 觸媒化學研究中心 外國人研究員 (1999, 08—2001, 03)
  6. 日本北海道大學 觸媒化學研究中心 博士後研究員 (1997, 08—1999, 07)

專長

  1. 無機化學
  2. 有機金屬化學
  3. 均相及異相催化

研究興趣

學術與著作

 

  1. Noriyuki Suzuki*, Shun Koyama, Rina Koike, Nozomu Ebara, Rikito Arai, Yuko Takeoka, Masahiro Rikukawa, Fu-Yu Tsai* “Palladium-Catalyzed Mizoroki–Heck and Copper-Free Sonogashira Coupling Reactions in Water Using Thermoresponsive Polymer Micelles” Polymers 2021, 13, 2717.
  2. Ya-Ting Chang, Ling-Jun Liu, Wen-Sheng Peng, Lin-Ting Lin, Yi-Tsu Chan, Fu-Yu Tsai* Stille Coupling for the Synthesis of Isoflavones by a Reusable Palladium Catalyst in Water J. Chin. Chem. Soc. 2021, 68, 469–475.
  3. Chung-Min Huang, Wen-Sheng Peng, Ling-Jun Liu, Chien-Chi Wu, Fu-Yu Tsai* “Iron-Catalyzed Conjugate Addition of Aryl Iodides onto Activated Alkenes under Air in Water” Catalysts 2020, 10, 1320.
  4. Noriyuki Suzuki*, Taiga Takabe, Yoshiko Yamauchi, Shun Koyama, Rina Koike, Masahiro Rikukawa, Wei-Ting Liao, Wen-Sheng Peng, Fu-Yu Tsai* “Palladium-catalyzed Mizoroki-Heck reactions in water using thermoresponsive polymer micelles” Tetrahedron 2019, 75, 1351–1358.
  5. Han-Sheng Lee, Shao-Hsuan Pai, Wei-Ting Liao, Xin-Jing Yang, Fu-Yu Tsai* “Mono and Double Mizoroki-Heck Reaction of Aryl Halides with Dialkyl Vinylphosphonates using a Reusable Palladium Catalyst under Aqueous Medium” RSC Adv. 2017, 7, 3429334299.
  6. Yu-Chi Chen, Chien-Chi Wu, Wei-Ting Liao, Ling-Jun Liu, Fu-Yu Tsai* “A Reusable Palladium/Cationic 2,2’-bipyridyl System-Catalyzed Double Mizoroki-Heck Reaction in Water” Catalysts 2017, 7, 177.
  7. Wei-Yi Wu, Ling-Jun Liu, Fen-Ping Chang, Yu-Lun Cheng, Fu-Yu Tsai* “A Highly Efficient and Reusable Palladium(II)/Cationic 2,2’-Bipyridyl-Catalyzed Stille Coupling in Water” Molecules 2016, 21, 1205.
  8. Cheng-Yuan Liu, Ying-Ho Chen, Chih-Hao Chen, Ming-Shiuan Yu, Fu-Yu Tsai*, Tiow-Gan Ong* Selective C(8)–H Activation of Imidazopyridines Mediated by Cooperative Nickel–Aluminum Catalysis” Synthesis 2016, 48, 27812788.
  9. Wei-Ting Liao, Xin-Jing Yang, Ya-Yi Tseng, Chien-Chi Wu, Ling-Jun Liu, Fu-Yu Tsai* Mizoroki–Heck Reaction of Aryl Halides and Dialkyl Allylphosphonates in Water Catalyzed by Reusable Palladium Nanoparticles” Asian J. Org. Chem. 2015, 4, 11121119.
  10. Ming-Shiuan Yu, Wei-Chih Lee, Chih-Hao Chen, Fu-Yu Tsai, Tiow-Gan Ong* “Controlled Regiodivergent CH Bond Activation of Imidazo[1,5-a]pyridine via Synergistic Cooperation between Aluminum and Nickel” Org. Lett. 2014, 16, 48264829.
  11. Ai-Jan Chen, I-Jui Hsu, Wei-Yi Wu, Yu-Tse Su, Fu-Yu Tsai*, Chung-Yuan Mou* A fluorescent organic nanotube assembled from a novel (p-phenylene ethynylene) based di-cationic amphiphiles Langmuir 2013, 29, 2580–2587.
  12. Wei-Yi Wu, Tze-Chiao Lin, Tamotsu Takahashi, Fu-Yu Tsai*, Chung-Yuan Mou* “Palladium Bipyridyl Complex Grafted on Nanosized MCM-41 as a Heterogeneous Catalyst for Negishi Coupling” ChemCatChem 2013, 5, 1011–1019.
  13. Sheng-Wen Tsai, Shao-Hsien Huang, Han-Sheng Lee, Fu-Yu Tsai* “A Reusable Palladium(II)/Cationic 2,2_-Bipyridyl Catalytic System for Hydroxycarbonylation of Aryl Iodides in Water” J. Chin. Chem. Soc. 2013, 60, 769772.
  14. Tzu-Ting Hung, Chun-Min Huang, Fu-Yu Tsai* Sonogashira-Hagihara Coupling towards Diaryl Alkynes Catalyzed by FeCl3.6H2O/Cationic 2,2’-Bipyridyl ChemCatChem 2012, 4, 540–545.
  15. Ming-Tzu Lan, Wei-Yi Wu, Kai-Lun Luo, Shao-Hsien Huang, Fu-Yu Tsai* Reusable and efficient CoCl2.6H2O/cationic 2,2’-bipyridyl system-catalyzed S-arylation of aryl halides with thiols in water under air RSC Adv. 2011, 1, 1751–1755.
  16. Tzu-Min Wu, Shao-Hsien Huang, Fu-Yu Tsai* A reusable CuSO4 • 5H2O/cationic 2,2’-bipyridyl system catalyzed homocoupling of terminal alkynes in water Appl. Organometal. Chem. 2011, 25, 395–399.
  17. Bo-Nan Lin, Shao-Hsien Huang, Wei-Yi Wu, Chung-Yuan Mou, Fu-Yu Tsai* Sonogashira reaction of aryl and heteroaryl halides with terminal alkynes catalyzed by a highly efficient and recyclable nanosized MCM-41 anchored palladium bipyridyl complex Molecules 2010, 15, 9157–9173.
  18. Shao-Hsien Huang, Tzu-Min Wu, Fu-Yu Tsai* “pH-Dependent conjugate addition of arylboronic acids to a,b-unsaturated enones catalyzed by a reusable palladium(II)/cationic 2,2’-bipyridyl system in water under air” Appl. Organometal. Chem. 2010, 24, 619–624.
  19. Yun-Hua Wang, Shao-Hsien Huang, Tze-Chiao Lin, Fu-Yu Tsai* “Rhodium(I)/cationic 2,2’-bipyridyl-catalyzed [2+2+2] cycloaddition of a,w-diynes with alkynes in water under air” Tetrahedron 2010, 66, 7136–7141.
  20. Shao-Hsien Huang, Jun-Rong Chen and Fu-Yu Tsai * “Palladium(II)/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water” Molecules 2010, 15, 315–330.
  21. Jun-You Chen, Tze-Chiao Lin, Szu-Chien Chen, Ai-Jan Chen, Chung-Yuan Mou, Fu-Yu Tsai* Highly-efficient and recyclable nanosized MCM−41 anchored palladium bipyridyl complex-catalyzed coupling of acyl chlorides and terminal alkynes for the formation of ynones Tetrahedron, 2009, 65, 10134–10141.
  22. Tzong-Huei Lee, Mei-Jhen Wang, Pi-Yu Chen, Tung-Ying Wu, Wu-Che Wen, Fu-Yu Tsai, Ching-Kuo Lee* Constituents of Polyalthia longifolia var. pendula J. Nat. Prod. 2009, 72, 19601963.
  23. Shao-Nung Chen, Tzu-Ting Hung, Tze-Chiao Lin, Fu-Yu Tsai* Reusable and Efficient CuI/TBAB-catalyzed Iodination of Treminal Alkynes in Water under Air J. Chin. Chem. Soc., 2009, 56, 1078–1081.
  24. Jun-You Chen, Szu-Chien Chen, Yun-Ju Tang, Chung-Yuan Mou, Fu-Yu Tsai* Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: a recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones J. Mol. Catal. A: Chem., 2009, 307, 8892.
  25. Wei-Yi Wu, Jui-Chan Wang, Fu-Yu Tsai* A reusable FeCl3«6H2O/cationic 2,2’-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions Green Chem., 2009, 11, 326–329.
  26. Shao-Nung Chen, Wei-Yi Wu, Fu-Yu Tsai* Homocoupling reaction of terminal alkynes catalyzed by a reusable cationic 2,2’-bipyridyl palladium(II)/CuI system in water Green Chem., 2009, 11, 269–274.
  27. Shao-Nung Chen, Wei-Yi Wu, Fu-Yu Tsai* Hiyama reaction of aryl bromides with arylsiloxanes catalyzed by a reusable palladium(II)/cationic bipyridyl system in water Tetrahedron, 2008, 64, 81648168. (Highlighted by Synfacts, 2009, 1, 0086)
  28. 吳威毅、蔡福裕 中孔洞二氧化矽材料擔附鈀金屬錯合物對於有機催化反應之研究 化學 2008, 66, 117125.
  29. Hsiung-Lin Tu, Fu-Yu Tsai*, Chung-Yuan Mou One-step synthesis of ordered mesostructural organic/silica nanocomposites with tunable fluorescence surfactants J. Mater. Chem., 2008, 18, 11711178.
  30. Yun-Hua Wang, Fu-Yu Tsai* Reusable Rhodium(I)/Cationic Bipyridyl-catalyzed Polymerization of Phenylacetylenes in Water under Aerobic Conditions Chem. Lett., 2007, 14921493.
  31. Fu-Yu Tsai*, Bo-Nan Lin, Ming-Jie Chen, Chung-Yuan Mou, Shiuh-Tzung Liu Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction Tetrahedron, 2007, 63, 43044309.
  32. Wei-Yi Wu, Shao-Nung Chen, Fu-Yu Tsai* Recyclable and highly active cationic 2,2’-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water Tetrahedron Lett., 2006, 47, 9267–9270.
  33. Fu-Yu Tsai, Hsiung-Lin Tu, Chung-Yuan Mou* Nonionic fluorescent oligomeric surfactant for ordered mesoporous silica structure J. Mater. Chem., 2006, 16, 348–350.
  34. 蔡福裕有機共軛高分子/中孔洞二氧化矽複合材料的合成與其性質化學, 2005, 63, 261–268.
  35. Fu-Yu Tsai, Chen-Lin Wu, Chung-Yuan Mou*, Man-Chien Chao, Hong-Ping Lin, Shiuh-Tzung Liu* Palladium bipyridyl complex anchored on nanosized MCM-41 as a highly efficient and recyclable catalyst for Heck reaction Tetrahedron Lett., 2004, 45, 7503–7506.

加入北科大前之期刊論文

  1. H. Wang, F.-Y. Tsai, K. Nakajima, T. Takahashi* Evidence for transmetalation of zirconacyclopentadiene to cobalt complex” Chem. Lett., 2002, 578579.
  2. W.-C. Chiang, F.-Y. Tsai, Y.-C. Cheng, G.-H. Lee, Y. Wang, J.-T. Chen* “Organometallic sulfato- and phosphate- allyl complexes synthesized from regioselective addition of oxyacids to an h3-allenyl/propargyl complex” Inorg. Chim. Acta, 2002, 334, 213218.
  3. T. Takahashi*, F.-Y. Tsai, Y. Li, H. Wang, Y. Kondo, M. Yamanaka, K. Nakajima, M. Kotora Selective Preparation of Pyridines, Pyridones, and Iminopyridines from Two Different Alkynes via Azazirconacycles J. Am. Chem. Soc., 2002, 124, 50595067.
  4. T. Takahashi*, F.-Y. Tsai, Y. Li, K. Nakajima “Reaction of Zirconacyclopentadienes with CO and Isonitriles” Organometallics, 2001, 20, 41224125.
  5. Y. Li, Y. Ura, F.-Y. Tsai, F. Xu, T. Takahashi* “Preparation of Benzoheterocycles Containing Group 14 Elements Using Zirconacyclopentadienes” Heterocycles, 2001, 54, 943955.
  6. T. Takahashi*, Y. Li, F.-Y. Tsai, K. Nakajima Cyclopentenone Formation by Regioselective Intermolecular Coupling of Trisubstituted Alkenes, Alkynes, and Isocyanates Organometallics, 2001, 20 595597.
  7. H. Wang, F.-Y. Tsai, T. Takahashi* “Nickel-Catalyzed Coupling Reaction of Zirconacyclopentadienes with Two Alkynyl Halides: Formation of Multi-Substituted Arylalkynes” Chem. Lett., 2000, 14101411.
  8. T. Takahashi*, F.-Y. Tsai, M. Kotora Selective Formation of Substituted Pyridines from Two Different Alkynes and a Nitrile: Novel Coupling Reaction of Azazirconacyclopentadienes with Alkynes J. Am. Chem. Soc., 2000, 122, 49944995.
  9. Y. Ura, Y. Li, F.-Y. Tsai, K. Nakajima, M. Kotora, T. Takahashi* “Preparation of Sn-, Ge-, and Si-Heterocycles from Zirconacycles” Heterocycles, 2000, 52, 11711189.
  10. T. Takahashi*, F.-Y. Tsai, Y. Li, K. Nakajima, M. Kotora “Carbon-Carbon Bond Formation Reaction of Zirconacyclopentadienes with Alkynes in the Presence of Ni(II)-Complexes” J. Am. Chem. Soc., 1999, 121, 1109311100.
  11. T. Takahashi*, F.-Y. Tsai, Y. Li “A Convenient Preparative Method of Dibromoterphenyl and Bis(bromophenyl)diene Monomers Using Zirconacyclopentadienes” Chem. Lett., 1999, 11731174.
  12. M. Kotora, M. Ishikawa, F.-Y. Tsai, T. Takahashi* Halogen-Dependent Coupling Reaction of Alkynes with (Z)-3-Halopropenoates Catalyzed by Nickel” Tetrahedron, 1999, 55, 4969–4978.
  13. A.-J. Chen, C.-C. Su, F.-Y. Tsai, J.-J. Lee, T.-M. Huang, C.-S. Yang, G.-H. Lee, Y. Wang, J.-T. Chen* A New Stable Intermediary Mode Betweenh3-2-Aminoallyl Complexes and Metallacyclobutanimines. Synthesis and Structure Characteristic of h3-Azatrimethylenemethane and N-protonated, N-alkylated, N-arylated h3-Azatrimethylenemethane Complexes of Pt and Pd J. Organomet. Chem., 1998, 569, 3954.
  14. F.-Y. Tsai, H.-W. Chen, J.-T. Chen* “Regioselective Attack of a Soft Carbon Nucleophile and Hydrogen Sulfide at the Central Carbon of a -Substituted h3-Allyl to Respectively Form h3-TMM and New Metallacyclis Thiacyclobutane Complexes” Organometallics, 1997, 16, 822823.
  15. F.-Y. Tsai, T.-M. Huang, J.-T. Chen*, G.-H. Lee, Y. Wang Regioselective Addition of Chalcugenol to an h3-Propargyl/Allenyl Complexes via Formation of the Carbon-Chalcogen Bond Leading to New Chalcugenolatoallyl Specices J. Organomet. Chem., 1996, 520, 8596.
  16. B.-C. Hsu, T.-M. Huang, F.-Y. Tsai, G.-L. Huang, M.-C. Cheng, G.-H. Lee, J.-T. Chen*, Y. Wang Insertion Reactions of Square-Planar Diorganoplatinum. 2. Carbonylation of trans-Pt(R)(R')(PPh3)2 Leading to cis-Pt(COR)(R')(PPh3)2 and Isomers of Pt(COR)(R'')(CO)(PPh3) J. Chin. Chem. Soc., 1994, 41, 763773.
  17. J.-T. Chen*, Y.-S. Yeh, C.-S. Yang, F.-Y. Tsai, G.-L. Huang, B.-C. Hsu, T.-M. Huang, Y.-S. Chen, G.-H. Lee, M.-C. Cheng, C.-C. Wang, Y. Wang Insertion-Reactions of Square-Planar Diorganoplatinum. 1 Scope and Mechanisms of Stereoselective Carbonylation, Decarbonylation, and Relevant Reactions of Alkyl Acyl, Aryl Acyl, Alkyl -Ketoacyl, Aryl -Ketoacyl, Diacyl, and Acyl -Ketoacyl Complexes Organometallics, 1994, 13, 48044824.
  18. J.-T. Chen*, W.-H. Tzeng, F.-Y. Tsai, M.-C. Cheng, Y. Wang Platinum Carbenes Formed via Intramolecular Acyl-Carbamoyl Coupling in  cis-Acyl -Ketoacyl Complexes of Platinum(II) Organometallics, 1991, 10, 39543955.

 

獎項

  1. 國立台北科技大學 工程學院 99年度傑出研究獎
  2. The IBC Top 100 Scientists 2010
  3. Who’s Who in the world 2011
  4. Who’s Who in the world 2010
  5. 中華民國斐陶斐榮譽學會會員

近三年內核定及申請中之研究計畫

# 計畫名稱 計畫內擔任之工作 起迄年月 補助或委託機構 執行情形
1

ppm等級水溶性鈀觸媒在水中高效率催化硝基芳烴還原及其一鍋反應形成聯芳基胺

計畫主持人

202108~202207

科技部

執行中

2

過渡金屬在水中催化芳基錫於炔基膦酸酯之氫芳基化與雙重芳基化反應及其應用

計畫主持人

202008~202107

科技部

已結案

3

高頻軟板用低介電樹脂材料結構設計與合成

計畫主持人

202012~202103

產學案

已結案

4

水溶性鐵觸媒催化硝基芳烴之還原與碳–碳鍵生成反應

計畫主持人

201908~202007

科技部

已結案

5

高頻樹脂開發

計畫主持人

201906~201912

產學案

已結案

6

水性工業塗料樹脂及分散劑化學結構研究

計畫主持人

201809~201902

產學案

已結案

7

利用有機膦酸酯為定位基形成高選擇性的1,1-雙取代乙烯

計畫主持人

201808~201907

科技部

已結案