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蔡福裕 教授

蔡福裕 博士

實驗室:奈米材料及有機金屬實驗室 詳細資料

學歷:

    國立台灣大學 化學博士
    國立台灣大學 化學碩士
    私立中原大學 化學學士

辦公室:分子館 2 樓 (02)27712171 #2437 

研究室:分子館 4 樓 (02)27712171 #2425

E-mail:fuyutsai@mail.ntut.edu.tw


簡歷

  1. 國立台北科技大學 教授 (2011, 08— )
  2. 國立台北科技大學 副教授 (2008, 02—2011, 07)
  3. 國立台北科技大學 助理教授 (2004, 02—2008, 01 )
  4. 國立臺灣大學 客座助理研究員 (2001, 04—2004, 01)
  5. 日本北海道大學 觸媒化學研究中心 外國人研究員 (1999, 08—2001, 03)
  6. 日本北海道大學 觸媒化學研究中心 博士後研究員 (1997, 08—1999, 07)

專長

  1. 無機化學
  2. 有機金屬化學
  3. 均相及異相催化

研究興趣

學術與著作

  1. Wei-Yi Wu, Ling-Jun Liu, Fen-Ping Chang, Yu-Lun Cheng, Fu-Yu Tsai* “A Highly Efficient and Reusable Palladium(II)/Cationic 2,2’-Bipyridyl-Catalyzed Stille Coupling in Water” Molecules 2016, 21, 1205.
  2. Cheng-Yuan Liu, Ying-Ho Chen, Chih-Hao Chen, Ming-Shiuan Yu, Fu-Yu Tsai*, Tiow-Gan Ong* “Selective C(8)–H Activation of Imidazopyridines Mediated by Cooperative Nickel–Aluminum Catalysis” Synthesis 2016, 48, 2781–2788.
  3. Wei-Ting Liao, Xin-Jing Yang, Ya-Yi Tseng, Chien-Chi Wu, Ling-Jun Liu, Fu-Yu Tsai* “Mizoroki–Heck Reaction of Aryl Halides and Dialkyl Allylphosphonates in Water Catalyzed by Reusable Palladium Nanoparticles” Asian J. Org. Chem. 2015, 4, 1112–1119.
  4. Ming-Shiuan Yu, Wei-Chih Lee, Chih-Hao Chen, Fu-Yu Tsai, Tiow-Gan Ong* “Controlled Regiodivergent C−H Bond Activation of Imidazo[1,5-a]pyridine via Synergistic Cooperation between Aluminum and Nickel” Org. Lett. 2014, 16, 4826–4829.
  5. Ai-Jan Chen, I-Jui Hsu, Wei-Yi Wu, Yu-Tse Su, Fu-Yu Tsai*, Chung-Yuan Mou* “A fluorescent organic nanotube assembled from a novel (p-phenylene ethynylene) based di-cationic amphiphiles” Langmuir 2013, 29, 2580–2587.
  6. Wei-Yi Wu, Tze-Chiao Lin, Tamotsu Takahashi, Fu-Yu Tsai*, Chung-Yuan Mou* “Palladium Bipyridyl Complex Grafted on Nanosized MCM-41 as a Heterogeneous Catalyst for Negishi Coupling” ChemCatChem 2013, 5, 1011–1019.
  7. Sheng-Wen Tsai, Shao-Hsien Huang, Han-Sheng Lee, Fu-Yu Tsai* “A Reusable Palladium(II)/Cationic 2,2_-Bipyridyl Catalytic System for Hydroxycarbonylation of Aryl Iodides in Water” J. Chin. Chem. Soc. 2013, 60, 769–772.
  8. Tzu-Ting Hung, Chun-Min Huang, Fu-Yu Tsai* “Sonogashira-Hagihara Coupling towards Diaryl Alkynes Catalyzed by FeCl3.6H2O/Cationic 2,2’-Bipyridyl” ChemCatChem 2012, 4, 540–545.
  9. Ming-Tzu Lan, Wei-Yi Wu, Kai-Lun Luo, Shao-Hsien Huang, Fu-Yu Tsai* “Reusable and efficient CoCl2.6H2O/cationic 2,2’-bipyridyl system-catalyzed S-arylation of aryl halides with thiols in water under air” RSC Adv. 2011, 1, 1751–1755.
  10. Tzu-Min Wu, Shao-Hsien Huang, Fu-Yu Tsai* “A reusable CuSO4 • 5H2O/cationic 2,2’-bipyridyl system catalyzed homocoupling of terminal alkynes in water” Appl. Organometal. Chem. 2011, 25, 395–399.
  11. Bo-Nan Lin, Shao-Hsien Huang, Wei-Yi Wu, Chung-Yuan Mou, Fu-Yu Tsai* “Sonogashira reaction of aryl and heteroaryl halides with terminal alkynes catalyzed by a highly efficient and recyclable nanosized MCM-41 anchored palladium bipyridyl complex” Molecules 2010, 15, 9157–9173.
  12. Shao-Hsien Huang, Tzu-Min Wu, Fu-Yu Tsai* “pH-Dependent conjugate addition of arylboronic acids to a,b-unsaturated enones catalyzed by a reusable palladium(II)/cationic 2,2’-bipyridyl system in water under air” Appl. Organometal. Chem. 2010, 24, 619–624.
  13. Yun-Hua Wang, Shao-Hsien Huang, Tze-Chiao Lin, Fu-Yu Tsai* “Rhodium(I)/cationic 2,2’-bipyridyl-catalyzed [2+2+2] cycloaddition of a,w-diynes with alkynes in water under air” Tetrahedron 2010, 66, 7136–7141.
  14. Shao-Hsien Huang, Jun-Rong Chen and Fu-Yu Tsai * “Palladium(II)/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water” Molecules 2010, 15, 315–330.
  15. Jun-You Chen, Tze-Chiao Lin, Szu-Chien Chen, Ai-Jan Chen, Chung-Yuan Mou, Fu-Yu Tsai* “Highly-efficient and recyclable nanosized MCM−41 anchored palladium bipyridyl complex-catalyzed coupling of acyl chlorides and terminal alkynes for the formation of ynones” Tetrahedron, 2009, 65, 10134–10141.
  16. Tzong-Huei Lee, Mei-Jhen Wang, Pi-Yu Chen, Tung-Ying Wu, Wu-Che Wen, Fu-Yu Tsai, Ching-Kuo Lee* “Constituents of Polyalthia longifolia var. pendula” J. Nat. Prod. 2009, 72, 1960–1963.
  17. Shao-Nung Chen, Tzu-Ting Hung, Tze-Chiao Lin, Fu-Yu Tsai* “Reusable and Efficient CuI/TBAB-catalyzed Iodination of Treminal Alkynes in Water under Air” J. Chin. Chem. Soc., 2009, 56, 1078–1081.
  18. Jun-You Chen, Szu-Chien Chen, Yun-Ju Tang, Chung-Yuan Mou, Fu-Yu Tsai* “Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: a recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones” J. Mol. Catal. A: Chem., 2009, 307, 88–92.
  19. Wei-Yi Wu, Jui-Chan Wang, Fu-Yu Tsai* “A reusable FeCl3«6H2O/cationic 2,2’-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions” Green Chem., 2009, 11, 326–329.
  20. Shao-Nung Chen, Wei-Yi Wu, Fu-Yu Tsai* “Homocoupling reaction of terminal alkynes catalyzed by a reusable cationic 2,2’-bipyridyl palladium(II)/CuI system in water” Green Chem., 2009, 11, 269–274.
  21. Shao-Nung Chen, Wei-Yi Wu, Fu-Yu Tsai* “Hiyama reaction of aryl bromides with arylsiloxanes catalyzed by a reusable palladium(II)/cationic bipyridyl system in water” Tetrahedron, 2008, 64, 8164–8168. (Highlighted by Synfacts, 2009, 1, 0086)
  22. 吳威毅、蔡福裕 “中孔洞二氧化矽材料擔附鈀金屬錯合物對於有機催化反應之研究” 化學 2008, 66, 117–125.
  23. Hsiung-Lin Tu, Fu-Yu Tsai*, Chung-Yuan Mou “One-step synthesis of ordered mesostructural organic/silica nanocomposites with tunable fluorescence surfactants” J. Mater. Chem., 2008, 18, 1171–1178.
  24. Yun-Hua Wang, Fu-Yu Tsai* “Reusable Rhodium(I)/Cationic Bipyridyl-catalyzed Polymerization of Phenylacetylenes in Water under Aerobic Conditions” Chem. Lett., 2007, 1492–1493.
  25. Fu-Yu Tsai*, Bo-Nan Lin, Ming-Jie Chen, Chung-Yuan Mou, Shiuh-Tzung Liu “Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction” Tetrahedron, 2007, 63, 4304–4309.
  26. Wei-Yi Wu, Shao-Nung Chen, Fu-Yu Tsai* “Recyclable and highly active cationic 2,2’-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water” Tetrahedron Lett., 2006, 47, 9267–9270.
  27. Fu-Yu Tsai, Hsiung-Lin Tu, Chung-Yuan Mou* “Nonionic fluorescent oligomeric surfactant for ordered mesoporous silica structure” J. Mater. Chem., 2006, 16, 348–350.
  28. 蔡福裕“有機共軛高分子/中孔洞二氧化矽複合材料的合成與其性質”化學, 2005, 63, 261–268.
  29. Fu-Yu Tsai, Chen-Lin Wu, Chung-Yuan Mou*, Man-Chien Chao, Hong-Ping Lin, Shiuh-Tzung Liu* “Palladium bipyridyl complex anchored on nanosized MCM-41 as a highly efficient and recyclable catalyst for Heck reaction” Tetrahedron Lett., 2004, 45, 7503–7506.
  30. H. Wang, F.-Y. Tsai, K. Nakajima, T. Takahashi* “Evidence for transmetalation of zirconacyclopentadiene to cobalt complex” Chem. Lett., 2002, 578–579.
  31. W.-C. Chiang, F.-Y. Tsai, Y.-C. Cheng, G.-H. Lee, Y. Wang, J.-T. Chen* “Organometallic sulfato- and phosphate- allyl complexes synthesized from regioselective addition of oxyacids to an h3-allenyl/propargyl complex” Inorg. Chim. Acta, 2002, 334, 213–218.
  32. T. Takahashi*, F.-Y. Tsai, Y. Li, H. Wang, Y. Kondo, M. Yamanaka, K. Nakajima, M. Kotora “Selective Preparation of Pyridines, Pyridones, and Iminopyridines from Two Different Alkynes via Azazirconacycles” J. Am. Chem. Soc., 2002, 124, 5059–5067.
  33. T. Takahashi*, F.-Y. Tsai, Y. Li, K. Nakajima “Reaction of Zirconacyclopentadienes with CO and Isonitriles” Organometallics, 2001, 20, 4122–4125.
  34. Y. Li, Y. Ura, F.-Y. Tsai, F. Xu, T. Takahashi* “Preparation of Benzoheterocycles Containing Group 14 Elements Using Zirconacyclopentadienes” Heterocycles, 2001, 54, 943–955.
  35. T. Takahashi*, Y. Li, F.-Y. Tsai, K. Nakajima “Cyclopentenone Formation by Regioselective Intermolecular Coupling of Trisubstituted Alkenes, Alkynes, and Isocyanates” Organometallics, 2001, 20 595–597.
  36. H. Wang, F.-Y. Tsai, T. Takahashi* “Nickel-Catalyzed Coupling Reaction of Zirconacyclopentadienes with Two Alkynyl Halides: Formation of Multi-Substituted Arylalkynes” Chem. Lett., 2000, 1410–1411.
  37. T. Takahashi*, F.-Y. Tsai, M. Kotora “Selective Formation of Substituted Pyridines from Two Different Alkynes and a Nitrile: Novel Coupling Reaction of Azazirconacyclopentadienes with Alkynes” J. Am. Chem. Soc., 2000, 122, 4994–4995.
  38. Y. Ura, Y. Li, F.-Y. Tsai, K. Nakajima, M. Kotora, T. Takahashi* “Preparation of Sn-, Ge-, and Si-Heterocycles from Zirconacycles” Heterocycles, 2000, 52, 1171–1189.
  39. T. Takahashi*, F.-Y. Tsai, Y. Li, K. Nakajima, M. Kotora “Carbon-Carbon Bond Formation Reaction of Zirconacyclopentadienes with Alkynes in the Presence of Ni(II)-Complexes” J. Am. Chem. Soc., 1999, 121, 11093–11100.
  40. T. Takahashi*, F.-Y. Tsai, Y. Li “A Convenient Preparative Method of Dibromoterphenyl and Bis(bromophenyl)diene Monomers Using Zirconacyclopentadienes” Chem. Lett., 1999, 1173–1174.
  41. M. Kotora, M. Ishikawa, F.-Y. Tsai, T. Takahashi* “Halogen-Dependent Coupling Reaction of Alkynes with (Z)-3-Halopropenoates Catalyzed by Nickel” Tetrahedron, 1999, 55, 4969–4978.
  42. A.-J. Chen, C.-C. Su, F.-Y. Tsai, J.-J. Lee, T.-M. Huang, C.-S. Yang, G.-H. Lee, Y. Wang, J.-T. Chen* “A New Stable Intermediary Mode Betweenh3-2-Aminoallyl Complexes and Metallacyclobutanimines. Synthesis and Structure Characteristic of h3-Azatrimethylenemethane and N-protonated, N-alkylated, N-arylated h3-Azatrimethylenemethane Complexes of Pt and Pd“ J. Organomet. Chem., 1998, 569, 39–54.
  43. F.-Y. Tsai, H.-W. Chen, J.-T. Chen* “Regioselective Attack of a Soft Carbon Nucleophile and Hydrogen Sulfide at the Central Carbon of a -Substituted h3-Allyl to Respectively Form h3-TMM and New Metallacyclis Thiacyclobutane Complexes” Organometallics, 1997, 16, 822–823.
  44. F.-Y. Tsai, T.-M. Huang, J.-T. Chen*, G.-H. Lee, Y. Wang “Regioselective Addition of Chalcugenol to an h3-Propargyl/Allenyl Complexes via Formation of the Carbon-Chalcogen Bond Leading to New Chalcugenolatoallyl Specices” J. Organomet. Chem., 1996, 520, 85–96.
  45. B.-C. Hsu, T.-M. Huang, F.-Y. Tsai, G.-L. Huang, M.-C. Cheng, G.-H. Lee, J.-T. Chen*, Y. Wang “Insertion Reactions of Square-Planar Diorganoplatinum. 2. Carbonylation of trans-Pt(R)(R')(PPh3)2 Leading to cis-Pt(COR)(R')(PPh3)2 and Isomers of Pt(COR)(R'')(CO)(PPh3)” J. Chin. Chem. Soc., 1994, 41, 763–773.
  46. J.-T. Chen*, Y.-S. Yeh, C.-S. Yang, F.-Y. Tsai, G.-L. Huang, B.-C. Hsu, T.-M. Huang, Y.-S. Chen, G.-H. Lee, M.-C. Cheng, C.-C. Wang, Y. Wang “Insertion-Reactions of Square-Planar Diorganoplatinum. 1 Scope and Mechanisms of Stereoselective Carbonylation, Decarbonylation, and Relevant Reactions of Alkyl Acyl, Aryl Acyl, Alkyl -Ketoacyl, Aryl -Ketoacyl, Diacyl, and Acyl -Ketoacyl Complexes” Organometallics, 1994, 13, 4804–4824.
  47. J.-T. Chen*, W.-H. Tzeng, F.-Y. Tsai, M.-C. Cheng, Y. Wang “Platinum Carbenes Formed via Intramolecular Acyl-Carbamoyl Coupling in  cis-Acyl -Ketoacyl Complexes of Platinum(II)” Organometallics, 1991, 10, 3954–3955.

獎項

  1. The IBC Top 100 Scientists 2010
  2. Who’s Who in the world 2011
  3. Who’s Who in the world 2010
  4. 中華民國斐陶斐榮譽學會會員

近三年內核定及申請中之研究計畫

# 計畫名稱 計畫內擔任之工作 起迄年月 補助或委託機構 執行情形
1 由芳香基取代烯丙基有機膦酸酯合成高共軛材料 主持人 201608~201707 科技部 執行中
2 水相中以過渡金屬催化有機膦酸酯及有機與芳香鹵化物或有機金屬試劑之耦合反應 主持人 201508~201607 科技部 已結案
3 高頻用低介電樹脂材料結構設計與合成 主持人 201503~201509 工研院 已結案
4 方扎鹵銨的合成 主持人 201503~201509 產學案 已結案
5 高效率, 可重覆使用之附載型金屬氧化物與水溶性觸媒系統研究與開發(3/3) 主持人 201408~201507 科技部 已結案